EyeToy: Groove:
Master level difficulty: 
To unlock as master difficulty, get an A in one of the tracks. You will then have a new difficulty level. It is (as far as I can tell) exactly like hard mode but with less warning when the heads will appear. 

Track 21-25 
Complete tracks 1-20 all the way through on any mode.

Unlock Songs 23-28 (NTSC Version):
Complete the first 23 songs on any difficulty.